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Hazard Communication (Pictograms) HAZCOM

 


The Hazard Communication (HazCom) Standard in the U.S. (29 CFR 1910.1200), aligned with the Globally Harmonized System (GHS), uses a set of nine standardized pictograms to convey chemical hazards quickly and visually. These pictograms appear on container labels and in Section 2 of Safety Data Sheets (SDS).

Unlike DOT placards (which are diamond-shaped and used on vehicles for transport), GHS pictograms are also red-bordered diamonds with a black symbol on a white background. They are designed to be immediately recognizable regardless of language.

Below are the nine GHS pictograms, grouped by the hazard category they represent.


Health Hazards

PictogramHazard Class
https://www.osha.gov/sites/default/files/2019-12/ghs_skull_crossbones.pngAcute Toxicity (fatal or toxic if swallowed, inhaled, or in contact with skin)
https://www.osha.gov/sites/default/files/2019-12/ghs_health_hazard.pngCarcinogenicityRespiratory SensitizerReproductive ToxicitySpecific Target Organ Toxicity (Single/Repeated Exposure)Germ Cell MutagenicityAspiration Hazard
https://www.osha.gov/sites/default/files/2019-12/ghs_corrosion.pngSkin Corrosion / BurnsEye DamageCorrosive to Metals
https://www.osha.gov/sites/default/files/2019-12/ghs_exclamation.pngIrritant (skin/eye), Skin SensitizerAcute Toxicity (harmful)Narcotic EffectsRespiratory Tract IrritationHazardous to Ozone Layer (non-mandatory)

Physical Hazards

PictogramHazard Class
https://www.osha.gov/sites/default/files/2019-12/ghs_flame.pngFlammablesPyrophoricsSelf-HeatingEmits Flammable GasSelf-ReactivesOrganic Peroxides
https://www.osha.gov/sites/default/files/2019-12/ghs_flame_circle.pngOxidizers (liquids, solids, gases)
https://www.osha.gov/sites/default/files/2019-12/ghs_gas_cylinder.pngGases under Pressure (compressed, liquefied, refrigerated, dissolved)
https://www.osha.gov/sites/default/files/2019-12/ghs_corrosion.pngCorrosive to Metals (also listed under health, but applies to physical hazard)
https://www.osha.gov/sites/default/files/2019-12/ghs_exploding_bomb.pngExplosivesSelf-Reactives (Type A/B), Organic Peroxides (Type A/B)
https://www.osha.gov/sites/default/files/2019-12/ghs_environment.pngHazardous to the Aquatic Environment (this pictogram is not mandatory under OSHA’s HazCom Standard, but is part of the full GHS system)

Important Notes

  1. Signal Words accompany pictograms: “Danger” for more severe hazards, “Warning” for less severe.

  2. Not all hazards have a pictogram. For example, combustible dust and simple asphyxiants are covered under HazCom but do not have a designated pictogram.

  3. DOT vs. GHS Pictograms: While both use diamond shapes, DOT placards are used on transport vehicles (trucks, rail cars) and often have a four-digit UN/NA number. GHS pictograms appear on workplace labels (e.g. shipped containers, secondary containers) and are part of the overall Hazard Communication program.

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